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3DPrinting
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All valid concerns, thank you for raising them: this hadn't crossed my mind.
But I'm not too concerned for the following reasons:
My current pair of pool shoes are commercial models I thermo-reformed with hot air (if you're interested in that process, I can post a video if you'd like). Pool shoes are made of vinyl: let me tell you, reforming vinyl at close to decomposing temperature is a nasty toxic fumes affair. Whatever drawbacks TPU may have can't be any worse for my health.
They'll be used mostly underwater in chlorinated water for a couple of hours per week tops.
My feet don't sweat much anymore.