I wouldn't buy hardware from Aliexpress as it has a bit of a reputation.
Anyway I would go with the N100 as it supports 3200MT/s memory.
Why do you need so much ram in your NAS?
May I ask why this mobo comes with CPU? I guess CPU can be replaced, but I cant find that one sold independently. I have no experience with this kind of hardware, but seems like it could be cheaper to buy MBO and CPU from local store. But again, im used to desktop components only (kind of), this one could be better value for $
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