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I share your curiosity, but I don't have a ton of time to dig into this right now beyond the thought experiment. That's the reason for my slower responses :( Work is busy and the kids eat up most of free time.
You're right - the seal will directly impact bass. This is why the sound on some headphones will change fairly dramatically as you move your head around - you're breaking the seal. For me, the head position most likely to break the seal is turning my neck fully in one direction and looking up, but it can also happen with less extreme head motions depending on the cans. I could see volume also playing a role, since the air volume inside the pad is effectively a resonator and changes in air volume will impact how it resonates. I suspect the material of the cup itself will also play a role. Something dense/reflective, like leather, will likely sound somewhat different than say a suede or a microfiber. That was one reason why I was considering gyroid - it would be reasonably non-reflective.
Sounds like a similar motivator to my "I wish these didn't press on my glasses frames so hard" ;)
A pop-tube seems like it would be hard to print vertically oriented. I suspect it would move around some as you're printing thanks to not being very rigid. It wouldn't hurt to try it. Printing it sliced down the center and laying across the bed horizontally seems like it would be easier. I certainly hear you on the joys of TPU stringing, but if it's limited to the far ends of the print it shouldn't be too horrible to clean up. You could even design it a touch too long and cut the ends off.
Depending on the spacing of the tube crinkles, you might be able to line them up so your frames fit between them. You could also probably make one crinkle stick out a little less and line that up with your frames.
At this point, I have nothing but time. I'm also trying out a pair of 'real' ANC headphones, vs my office drone headset that happens to have defeatable ANC. They have ridiculously sized pads and they're actually pretty comfortable with glasses. I am somewhat tempted to type out a mini-review somewhere here, but have no idea where I would post it.